LABORATORY OF CATALYSIS OF POLYMERIZATION PROCESSES
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The laboratory was established in 2008 The stuff consists of 8 researchers including 3 Ph. Ds Phone :+375 (17) 209-51-75; 209-53-07
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main achievements:
synthesis of well-defined poly(styrene)s by living cationic polymerization using AlCl3-based initiating systems;
design of the new initiating systems for aqueous suspension and emulsion cationic polymerization of styrene, p-methoxystyrene, p-hydroxystyrene and cyclopentadiene;
synthesis of “highly reactive” polyisobutylene via cationic polymerization using a modified AlCl3-based initiating system;
creation of new catalysts for syndiospecific styrene polymerization and ring-opening polymerization of cyclic esters based on titanium complexes of dialkanolamine ligands
Developments:
technology of petroleum polymeric resins preparation by a catalytic method;
wasteless technology of petroleum polymerizate preparation by a catalytic method.
Main publications:
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1.1. Pouget E., Holgado-Garcia E., Vasilenko I.V., Kostjuk S.V., Campagne J.M., Ganachaud, F. / Oligomerization of Electron-Deficient Vinyl Monomers Through an Ate- Complex Mechanism: A New Role for B(C6F5)3 Lewis Acid // Macromol Rapid Commun, 2009, Vol. 30, 1128-1132.
2.2. Kostjuk S.V., Ortega E., Ganachaud F., Ameduri B., Boutevin B. / Anionic Ring–Opening Polymerization of Hexafluoropropylene Oxide using Alkali Metal Fluorides as Catalysts: a Mechanistic Study // Macromolecules 2009, Vol. 42, p. 612-619.
3.3. Radchenko A.V., Kostjuk S.V., Vasilenko I.V., Ganachaud F., Kaputsky F.N., Guillaneuf Y. / Kinetic study on the living/controlled cationic polymerization of p-methoxystyrene coinitiated by tris(pentafluorophenyl)borane // Journal of Polymer Science Part A: Polymer Chemistry 2008, Vol. 46, 6928-6939.
4.4. Kostjuk S.V., Radchenko A.V. Ganachaud F. / Controlled cationic polymerization of cyclopentadiene with B(C6F5)3 as a coinitiator in the presence of water // Journal of Polymer Science Part A: Polymer Chemistry 2008, Vol.46, issue 14, p. 4734-4747.
5.5. Vasilenko I.V., Kostjuk S.V., Kaputsky F.N., Nedorezova P.M., Aladyshev A.M. / Effect of different aluminum alkyls on the metallocene/methylaluminoxane catalyzed polymerization of higher a-olefins and styrene // Macromol Chem Phys 2008, Vol. 209, Issue 12, p. 1255-1265.
6.6. Radchenko A.V., Kostjuk S.V., Vasilenko I.V., Ganachaud F., Kaputsky F.N. / Controlled/living cationic polymerization of styrene with BF3OEt2 as coinitiator in the presence of water: improvements and limitations // European Polymer Journal 2007, Vol. 43, ¹6, p. 2576-2583.
7.7. Kostjuk S.V., Radchenko A.V., Ganachaud F. / Controlled/living cationic polymerization of p-methoxystyrene in solution and aqueous dispersion using tris(pentafluorophenyl)borane as a Lewis acid: acetonitrile does the job // Macromolecules 2007, Vol. 40, ¹3, p. 482-490.
8.8. Kostjuk S.V., Dubovik A.Yu., Vasilenko I.V., Frolov A.N., Kaputsky F.N. / Kinetic and mechanistic study of the quasiliving cationic polymerization of styrene in the 2-phenyl-2-propanol/AlCl3OBu2 initiating system // European Polymer Journal 2007, Vol. 43, ¹3, p. 968-979.
9.9. Vasilenko I.V., Kostjuk S.V., Gaponik L.V., Kaputsky F.N. / Copolymerization of styrene and 1-hexene with a TiCl4-Al(C6H13)3 Mg(C6H13)2 catalytic system // Polymer Science, Ser A 2007, Vol. 49, ¹4, p. 618-624.
10.10. Kostjuk S.V., Ganachaud F. / Cationic polymerization of styrene in solution and aqueous suspension using B(C6F5)3 as a water-tolerant Lewis acid // Macromolecules 2006, Vol. 39, ¹ 9, p. 3110-3113.
11.11. Vasilenko I.V., Kostjuk S.V./ The influence of cocatalysts on 1-hexene polymerization with various supported magnesium-titanium catalysts // Polymer Bulletin 2006, Vol. 57, ¹2, p. 129-138.
